Single-electron transistor of a single organic molecule with access to several redox states

By S. Kubatkin, A. Danilov, M. Hjort, J. Cornil, J. Brédas, N. Stuhr-Hansen, P. Hedegård, T. Bjørnholm. Nature, 2003

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Advances and challenges in single-molecule electron transport (2019, methodology): “Low-temperature experiments us- 48 ing in-situ deposition of the metal electrodes (Kubatkin et al., 2003), experiments using electromigration (Liang et al., 2002; Osorio et al., 2007b; Park et al., 2002), or three-terminal break junctions (Perrin et al., 2013), all demonstrate the sensitivity of…”
Electrostatic modification of novel materials (2006, background): “…more than two charge states of a SMT is generally extremely challenging, even in devices incorporating ultrathin aluminum-oxide gate dielectrics Park et al., 2000, 2002; Liang et al., 2002 , though multiple accessible redox states have been reported in a related technique Kubatkin et al., 2003 .”
Molecular transport junctions: vibrational effects (2006, background): “The latter situation is known as the Coulomb blockade regime in the nanodots literature [136–140, 242–247] and its molecular analogue is getting increasing attention in studies of molecular bridges with several accessible Topical Review oxidation states [28] [80] [86] [129] [248].”