Transition from Battery to Pseudocapacitor Behavior via Structural Water in Tungsten Oxide

By James B. Mitchell, W. C. Lo, A. Genç, James M. LeBeau, V. Augustyn. 2017

207 citations recorded by the source corpus.

The kinetics of energy storage in transition metal oxides are usually limited by solid-state diffusion, and the strategy most often utilized to improve their rate capability is to reduce ion diffusion distances by utilizing nanostructured materials. Here, another strategy for improving the kinetics of layered transition metal oxides by the presence of structural water is proposed. To investigate this strategy, the electrochemical energy storage behavior of a model hydrated layered oxide, WO3·2H2O, is compared with that of anhydrous WO3 in an acidic electrolyte. It is found that the presence of structural water leads to a transition from battery-like behavior in the anhydrous WO3 to ideally pseudocapacitive behavior in WO3·2H2O. As a result, WO3·2H2O exhibits significantly improved capacity retention and energy efficiency for proton storage over WO3 at sweep rates as fast as 200 mV s–1, corresponding to charge/discharge times of just a few seconds. Importantly, the energy storage of WO3·2H2O at such rates ...

Subfields: Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/bec65a207e773ca73477ad360d6bec650753bcb0