Core Level Spectroscopy of Solids

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X-ray absorption near-edge structure (XANES) spectroscopy (2014, methodology): “Consequently, the pre-edge features can thus be interpreted using ligand eld theory or charge transfer multiplet theory (cf., de Groot 2005; de Groot and Kotani 2008).”
Inelastic x-ray scattering by electronic excitations under high pressure (2008, methodology): “An extensive description of the multiplet approach can be found in Cowan (1981) while its application to core hole spectroscopy is the object of a recent work by de Groot and Kotani (2008).”
Chemical bonding and electronic-structure in MAX phases as viewed by X-ray spectroscopy and density functional theory (2016, methodology): “Particularly useful aspects of the XAS technique in TFY mode and the XES/RIXS techniques of great importance for probing buried layers [19] and nanolaminates such as MAX phases containing two or more different elements are the element selectivity and the large probe and information depth obtained in”
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides (2012, background): “ MnF 3 and two peaks, a1 and a2, for MnF 2 (Fig.3). While the Mn-L spectra are dominated by atomic multiplet effects, the ligand-K pre-edge features correspond mainly to spin states and crystal fields[23]. This is because the pre-edge stems from the excitation from ligand 1s core electron to the Leg”