Enzyme-like catalysis by molecularly imprinted polymers.

By G. Wulff. Chemical Reviews, 2002

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Fourty years of molecular imprinting in synthetic polymers: origin, features and perspectives (2013, background): “Catalytically active, imprinted particles obtained by suspension or emulsion polymerization are insoluble (similarly as bulk polymers), the observed rate enhancements in catalysis are in the same order of magnitude or somewhat higher compared to bulk polymers [36, 47, 48].”
Molecularly Imprinted Polymers: Present and Future Prospective (2011, background): “The polymer matrix obtained has cavities with a shape similar to the shape of the template used [72,167]; but the imprinting technology must also ensure the right placement of the functional groups in the binding sites in consideration of the type of catalytic process that they will assist [168].”
Characteristic and synthetic approach of molecularly imprinted polymer (2006, background): “In recent years, the u ses of monolithic media for superior chromatographic separation in high-performance liqu id chromatography and capillary electrochromatography have attracted considerable a ttention [94-102].”