A Relationship between Electron-Transfer Rates and Molecular Conduction †

By Abraham Nitzan. 2001

173 citations recorded by the source corpus.

This note discusses the relationship between a given intramolecular bridge-assisted electron-transfer rate and the corresponding zero bias molecular conduction of the same molecular species.

Subfields: Electrical and Electronic Engineering, Electrochemistry, Physical and Theoretical Chemistry

View Paper: https://www.semanticscholar.org/paper/f43a0e43224cdeb6132c90b60eb8a394490f8ed3

How researchers see this paper

The researchers whose trusted networks rank it highest, strongest advocate first. Every researcher gets a different order.

In Electrical and Electronic Engineering

1. Mark A. Ratner
2. Gianaurelio Cuniberti
3. T. O. S. University
4. Israel
5. Northwestern University School of Chemistry
6. Michael Galperin
7. Abraham Nitzan Department of Chemistry
8. Nongjian Tao

In Electrochemistry

1. Michael Galperin
2. Mark A. Ratner
3. Nongjian Tao

In Physical and Theoretical Chemistry

1. Gianaurelio Cuniberti
2. Mark A. Ratner
3. Nongjian Tao
4. Venera Khoromskaia
5. Anna I. Krylov
6. Heinz-Jürgen Flad
7. Boris N. Khoromskij
8. Wolfgang Hackbusch

Citations in the corpus

• Electron transport in molecular junctions (2006, background): “A relationship between charge transfer rate and conductance has been worked out by Nizta”
• Molecular transport junctions: vibrational effects (2006, background): “e approximate expression for the relationship between electron transfer rate kDA→ across a given molecular species and the low bias conduction g of the same species in the coherent transport regime is[23] 2 2 () ( ) 8 LRDA D A e gk π ≈ → ΓΓF (4) where ()L ΓD is the rate of electron transfer from the”
• Charge transport in DNA-based devices (2004, background): “The electronic structure of the investigated molecules is important [ 55 ,56] in indirect electrochemical measurements, as well as in the direct transport measurements.”