The thermodynamics of iron and magnesium partitioning between olivine and liquid: criteria for assessing and predicting equilibrium in natural and experimental systems

By M. Toplis. 2005

465 citations recorded by the source corpus.

Subfields: Biomaterials, Geophysics

View Paper: https://www.semanticscholar.org/paper/f28e467a4ab442d88ade70c0b23f29dec0055399

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In Biomaterials

1. S. Lambart
2. P. Schiano
3. H. Dalton
4. D. Laporte
5. K. Condie
6. Donald M. White
7. Jun Korenaga
8. T. Holland

In Geophysics

1. C. Herzberg
2. K. Condie
3. E. Jennings
4. S. Lambart
5. P. Schiano
6. H. Dalton
7. D. Laporte
8. Donald M. White

Citations in the corpus

• Experimental petrology of the basaltic shergottite Yamato‐980459: Implications for the thermal structure of the Martian mantle (2006, methodology): “However, Toplis (2005) found that DFe/DMg was only weakly dependent on pressure.”
• Nitrogen solubility in molten metal and silicate at high pressure and temperature (2012, background): “…and Eggins (2002) for several melt compositions in the CaO–MgO–Al2O3–SiO2 system, and by Holzheid et al. (1997) for melts in the anorthitediopside system and for komatiitic basalt with the assumption of no significant pressure effect on the activity coefficients in silicate melts (Toplis, 2005).”
• Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: implications for andesite genesis (2012, unknown): “Olivine grains near their low-temperature stability limit have KDs somewhat higher (0.33–0.37) than the commonly referenced value of 0.3 for basaltic liquids (Roeder and Emslie 1970; Toplis 2005).”
• Fate of Pyroxenite-derived Melts in the Peridotitic Mantle: Thermodynamic and Experimental Constraints (2012, result): “…and I16-10 in which the melt fraction is significantly higher, Ol crystals exceed 20 mm and pyroxene grains can reach a diameter of 10^ 15 mm. Fe^Mg exchange coefficients between Ol and melt are equal to 0·30 0·02, perfectly consistent with values predicted by Toplis’ (2005) model (0·31 0·01).”
• A Simple Thermodynamic Model for Melting of Peridotite in the System NCFMASOCr (2015, methodology): “The partitioning of Fe and Mg between olivine and melt was used to make small adjustments to the enthalpies of the foL and faL components to fit the relations seen as a function of pressure in the studies by Takahashi & Kushiro (1983) and Toplis (2005).”
• Heterogeneous distribution of H2O in the Martian interior: Implications for the abundance of H2O in depleted and enriched mantle sources (2016, background): “Instead, these recent studies examined apatite-melt exchange equilibria in a similar manner as is done for Fe-Mg exchange equilibrium between olivine and melt (e.g., Roeder and Emslie 1970; Toplis 2005; Filiberto and Dasgupta 2011).”
• Thermal history of the Earth and its petrological expression (2010, methodology): “Parental magma composition was determined for each lava by adding or subtracting olivine using 1 atm Fe–Mg partitioning from Toplis (2005) until the magma was in equilibrium with these olivine compositions.”