Multinuclear solid-state NMR of inorganic materials

By K. MacKenzie, Mark E. Smith. 2002

840 citations recorded by the source corpus.

Subfields: Condensed Matter Physics, Materials Chemistry, Spectroscopy

View Paper: https://www.semanticscholar.org/paper/ebc068e9f979e8d82337ef03376ce38387a32d15

How researchers see this paper

The researchers whose trusted networks rank it highest, strongest advocate first. Every researcher gets a different order.

In Condensed Matter Physics

1. K. MacKenzie
2. D. Neuville

In Materials Chemistry

1. J. Provis
2. S. A. Bernal
3. U. C. Melo
4. P. Lemougna
5. K. MacKenzie
6. D. Neuville
7. D. Massiot
8. V. Barbosa

In Spectroscopy

1. K. MacKenzie
2. L. Cormier
3. D. Neuville
4. D. Massiot
5. J. Provis

Citations in the corpus

• The role of iron in the formation of inorganic polymers (geopolymers) from volcanic ash: a 57Fe Mössbauer spectroscopy study (2013, result): “Either of these interpretations would provide an explanation of the observed Mössbauer parameters, and although they would tend to rule out the location of the ferric iron in the better-defined tetrahedral sites in geopolymers, they are not inconsistent with the known situation in other gels, for in”
• Characterisation of magnesium potassium phosphate cements blended with fly ash and ground granulated blast furnace slag (2015, background): “Aluminium-phosphate bonds are typically observed in (27)Al NMR spectra between 45 ppm and −25 ppm, with three main phosphate environments: Al(OP)4 centred at ~40 ppm, Al(OP)5 centred at ~10 ppm, and Al(OP)6 centred at ~−20 ppm [25].”
• Al coordination and speciation in calcium aluminosilicate glasses: Effects of composition determined by 27Al MQ-MAS NMR and Raman spectroscopy (2006, background): “(i) percalcic glasses (R=CaO/Al2O3>1) with high SiO2 content (>45 mol%): in this region, the Al NMR spectra are dominated by a strong contribution assigned to four-fold coordinated Al, Al, (higher chemical shift) and a small one attributed to five-fold coordinated Al, Al (lower chemical shift) (MacK”
• Solid-State Li NMR with Applications to the Translational Dynamics in Ion Conductors (2007, background): “The isotropic chemical shift is relatively small (it ranges from about 9 ppm to +3 ppm [240–242]) and, due to a possible interference with second-order quadrupolar effects in Li, is practically only discussed for Li.”
• Synthesis and thermal behaviour of potassium sialate geopolymers (2003, background): “2C) indicates the presence of considerably more unreacted metakaolinite, evidenced by a stronger octahedral resonance at 6 ppm and the residual broad metakaolinite peak at 27 ppm often attributed to five-coordinated Al–O [7].”
• A 27Al MAS NMR study of a sol–gel produced alumina: Identification of the NMR parameters of the θ-Al2O3 transition alumina phase (2007, background): “Al MAS NMR is a very commonly used structural probe [15,16], but there are relatively few detailed NMR studies of transition aluminas given their very widespread occurrence and importance [1,5,17–20].”