Synthesis of superfine high-entropy metal diboride powders

By D. Liu, T. Wen, Beilin Ye, Yanhui Chu. Scripta Materialia, 2019

153 citations recorded by the source corpus.

Abstract High-purity and superfine high-entropy metal diboride powders, namely (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B2, were successfully synthesized via a facile borothermal reduction method at 1973 K for the first time. The as-synthesized powders with an average particle size of ~310 nm had a single-crystalline hexagonal structure of metal diborides and simultaneously possessed high compositional uniformity from nanoscale to microscale. In addition, their formation mechanisms were well interpreted by analyzing the thermodynamics of the possible chemical reactions based on the first-principles calculations. This work will open up a new research field on the synthesis of high-entropy metal diboride powders.

Subfields: Mechanical Engineering, Mechanics of Materials

View Paper: https://www.semanticscholar.org/paper/ea0243b243a1701999532f558a402187c41376c3

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In Mechanical Engineering

  1. Jian Luo
  2. Andrew J. Wright
  3. Joshua Gild
  4. P. Hopkins
  5. Tyler J. Harrington
  6. Kenneth S. Vecchio

In Mechanics of Materials

  1. P. Hopkins

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