Ca and Na environments in Na2O–CaO–Al2O3–SiO2 glasses: influence of cation mixing and cation-network interactions.

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A computer simulation study of natural silicate melts. Part I: Low pressure properties (2007, background): “For Ca, the cation–oxygen distances in the simulated liquids are found close to those observed in soda lime alumi-nosilicate glasses (Cormier and Neuville, 2004), i.e. d (Ca–”
X-ray absorption near-edge structure (XANES) spectroscopy (2014, background): “There also appears to be an edge shift to lower energy with increasing Al/Na ratio, at least up to a ratio of 1.0 (McKeown et al. 1985), but the overall shape of the spectra are not affected signi cantly with Al substitution for Si (Cormier and Neuville 2004).”
Al speciation and Ca environment in calcium aluminosilicate glasses and crystals by Al and Ca K-edge X-ray absorption spectroscopy. (2004, background): “A comparison between XANES spectra of glasses and various crystalline minerals containing Ca in different local geometry (Cormier and Neuville, 2004) shows the sensitivity of the Ca k-edge to the local environment and indicates a great similarity between the Ca Kedges of glasses and anorthite.”
Viscosity, structure and mixing in (Ca, Na) silicate melts (2006, background): “The modification in network topology will provide new types of empty sites that could be used for Ca movements (Cormier and Neuville, 2004).”