On the mechanisms of precipitation of graphene on nickel thin films

By L. Baraton, Z. He, C. S. Lee, Costel Sorin Cojocaru, M. Chātelet, J. Maurice, Y. H. Lee, Didier Pribat. 2011

182 citations recorded by the source corpus.

Growth on transition metal substrates is becoming a method of choice to prepare large-area graphene foils. In the case of nickel, where carbon has a significant solubility, such a growth process includes at least two elementary steps: 1) carbon dissolution into the metal, and 2) graphene precipitation at the surface. Here, we dissolve calibrated amounts of carbon in nickel films, using carbon ion implantation, and annealing at 725°C or 900°C. We then use transmission electron microscopy to analyse the precipitation process in detail: the latter appears to imply carbon diffusion over large distances and at least two distinct microscopic mechanisms.

Subfields: Electrical and Electronic Engineering, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/e90e7084b7e0a8543a15eb8d82418c1d28b64c1b

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In Electrical and Electronic Engineering

  1. Francesco Bonaccorso
  2. Andrea C. Ferrari
  3. C. Backes
  4. Xiaodong Zhuang
  5. A. Ciesielski
  6. Paolo Samorì
  7. A. Castellanos-Gómez
  8. Xinliang Feng

In Materials Chemistry

  1. Kostas Kostarelos
  2. M. Prato
  3. Francesco Bonaccorso
  4. A. Bianco
  5. A. Castellanos-Gómez
  6. Jonathan N. Coleman
  7. Andrea C. Ferrari
  8. Paolo Samorì

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