Introduction to the Thermodynamics of Materials

By D. Gaskell. 2017

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A critical review of high entropy alloys and related concepts (2016, background): “However, the common tangent construct [40,42,43] shows that co-existing stable phases have compositions that are different from each other and also different from the alloy composition, so that Gibbs energies must be considered over a range of compositions.”
Viewpoint: metallurgical aspects of powder bed metal additive manufacturing (2016, methodology): “The Ellingham diagram can be used to determine the partial oxygen pressure conditions that suffice to prevent the formation of oxide layers as a function of temperature [4, 5].”
Part I: Theoretical predictions of preferential oxidation in refractory high entropy materials (2020, unknown): “id solution of HfO 2 and ZrO 2 , with a corresponding equilibrium pO 2 . The relevant reactions for each alloy constituent are: ��+ �2(�)↔��2 (9) �𝑟+�2(�)↔�𝑟�2 (10) Following Gaskell's approach [15], the pertinent reaction describing the equilibrium between the base metal constituents and th”