Anionic redox processes for electrochemical devices.

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Electronic defects in metal oxide photocatalysts (2022, background): “From a reactivity standpoint, the basic roles that defects play in surface chemistry are schematically represented in Figure 6a-d and can be categorized as follows: (a) the defect forms as part of the catalytic cycle and interaction with the electrolyte.(197,198) (b) The presence of defects ‘physica”
Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction (2016, background): “…migration triggered by the reactivity of the electrophilic oxidized surface oxygen with a nucleophile solvent molecule will serve the field of Li-ion batteries where positive electrodes such as Li-rich layered compounds exhibit the same oxygen oxidation 25,40–42 and surface reactivity process.”
Computation-Accelerated Design of Materials and Interfaces for All-Solid-State Lithium-Ion Batteries (2018, background): “Oxygen redox and oxygen loss at high voltages are known issues in oxide cathode materials.(112,113) Many SEs have equilibrium oxidation potentials higher than the equilibrium potentials of oxygen evolution reactions of Li2O and Li2O2 in Li-O2 batteries.”