Correlation between thermodynamical stabilities of metal borohydrides and cation electronegativites: First-principles calculations and experiments
By Y. Nakamori, K. Miwa, A. Ninomiya, Haiwen Li, Nobuko Ohba, S. Towata, A. Züttel, S. Orimo. 2006
434 citations recorded by the source corpus.
Subfields: Atomic and Molecular Physics, and Optics, Catalysis, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/e7ab41abac9e024a1b0485ec37b0640c2e2f8a55
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In Atomic and Molecular Physics, and Optics
In Catalysis
In Materials Chemistry
Citations in the corpus
- Recent Progress in Metal Borohydrides for Hydrogen Storage (2011, methodology): “The thermodynamic stabilities for the series of metal borohydrides M(BH4)n (M = Li, Na, K, Mg, Ca, Sc, Zr, Hf, Cu, Zn, and Al; n = 1–4) have been systematically investigated using first-principles calculations [104].”
- Hydrogen: the future energy carrier (2008, background): “The empirical equation for the enthalpy of formation (Nakamori et al. 2006) of the tetrahydroboranates is DH (kJ mol−1 BH4) = 247.”
- Complex metal hydrides for hydrogen, thermal and electrochemical energy storage (2017, background): “Additionally, a relationship between the Pauling electronegativity of the metal cation and the thermal stability of the metal borohydride has been established as higher electronegativity results in lower decomposition temperature, see Figure 2 [2,110,111].”