Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry

By S. Sutton, J. Karner, J. Papike, J. Delaney, C. Shearer, Matthew Newville, P. Eng, Mark Rivers, Melinda Darby Dyar. 2005

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The Role of Water in Generating the Calc-alkaline Trend: New Volatile Data for Aleutian Magmas and a New Tholeiitic Index (2010, background): “…from SKa shifts (Irazu¤ , Benjamin et al., 2007; Arenal, Wade et al., 2006) and mXANES measurements of Fe3þ/ Fe (Sarigan, Kelley & Cottrell, 2009), although some record lower fO2 FMQ þ0·5 (Par|¤cutin, Kelley & Cottrell, 2009; Stromboli, Me¤ trich et al., 2002; Cerro Negro, Sutton et al., 2005).”
Redox Conditions in the Solar Nebula: Observational, Experimental, and Theoretical Constraints (2008, background): “In a V-doped CMAS glass synthesized at fO2 = 10 -18 and 1583K, Sutton et al. (2005) also found that a large proportion of the V, ~25%, is V2+.”
X-ray absorption near-edge structure (XANES) spectroscopy (2014, unknown): “Vanadium (V): Nabavi et al. 1990; Abbate et al. 1993; Giuli et al. 2004; Sutton et al. 2005; Simon et al. 2007; Burke et al. 2012; Höche et al. 2013.”