Three-dimensional network structure assembled by g-C3N4 nanorods for improving visible-light photocatalytic performance

By Wenjia Luo, Xianjie Chen, Zhen Wei, Di Liu, W. Yao, Yongfa Zhu. Applied Catalysis B: Environmental, 2019

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Abstract Bulk g-C3N4 has suffered from its low specific surface area and high recombination of photogenerated electron-hole pairs. Herein, three-dimensional network structure g-C3N4 assembled by nanorods (3D g-C3N4 NR) was successfully fabricated via a chemical tailoring route. The as-prepared 3D g-C3N4 NR exhibits lager specific surface areas (6.7 times of bulk g-C3N4) and faster charge carrier transfer kinetics. Hence, the visible-light photocatalytic activities for degradation of phenol and hydrogen evolution over 3D g-C3N4 NR are evidently enhanced, 4.3 and 5.9 times as high as that of bulk g-C3N4, respectively. Briefly, this work throws light on structural tuning of carbon nitride polymer photocatalysts for improved solar energy capture and conversion.

Subfields: Electrical and Electronic Engineering, Materials Chemistry, Renewable Energy, Sustainability and the Environment

View Paper: https://www.semanticscholar.org/paper/e72e3e0134b0ff3ed6dbfe8854b492b25365f10e