Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene

By Kanit Hantanasirisakul, Mohamed Alhabeb, Alexey Lipatov, K. Maleski, B. Anasori, P. Salles, Chanoknan Ieosakulrat, P. Pakawatpanurut, Alexander Sinitskii, S. May and 1 more. Chemistry of Materials, 2019

232 citations recorded by the source corpus.

MXenes, a relatively new class of two-dimensional (2D) transition-metal carbides, carbonitrides, and nitrides, exhibit unique properties such as high electronic conductivity, a wide range of optical characteristics, hydrophilicity, and mechanical stability. Because of the high electronic conductivity, MXenes have shown promise in many applications, such as energy storage, electromagnetic interference shielding, antennas, and transparent coatings. 2D titanium carbide (Ti3C2Tx, where Tx represents surface terminations), the first discovered and most studied MXene, has the highest electronic conductivity exceeding 10 000 S cm–1. There have been several efforts to alter the conductivity of MXenes, such as manipulation of the transition-metal layer and control of surface terminations. However, the impact of the C and N site composition on electronic transport has not been explored. In this study, the effects of synthesis methods on optoelectronic properties of 2D titanium carbonitride, Ti3CNTx, were systematic...

Subfields: Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/e7216cbc12bb8ffb1fdd5b8188bf019914d3fb1c

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In Materials Chemistry

  1. Yury Gogotsi
  2. J. Rosen
  3. Armin VahidMohammadi
  4. C. Shuck
  5. Kanit Hantanasirisakul
  6. K. Maleski
  7. A. Sarycheva
  8. Mark Anayee

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