Photocatalysis with TiO2 Nanotubes: “Colorful” Reactivity and Designing Site-Specific Photocatalytic Centers into TiO2 Nanotubes

By Xuemei Zhou, Ning Liu, P. Schmuki. 2017

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Photocatalytic reactions on TiO2 have recently gained an enormous resurgence because of various new strategies and findings that promise to drastically increase efficiency and specificity of such reactions by modifications of the titania scaffold and chemistry. In view of geometry, in particular, anodic TiO2 nanotubes have attracted wide interest, as they allow a high degree of control over the separation of photogenerated charge carriers not only in photocatalytic reactions but also in photoelectrochemical reactions. A key advantage of ordered nanotube arrays is that nanotube modifications can be embedded site specifically into the tube wall; that is, cocatalysts, doping species, or junctions can be placed at highly defined desired locations (or with a desired regular geometry or pattern) along the tube wall. This allows an unprecedented level of engineering of energetics of reaction sites for catalytic and photocatalytic reactions, which target not only higher efficiencies but also the selectivity of re...

Subfields: Materials Chemistry, Renewable Energy, Sustainability and the Environment

View Paper: https://www.semanticscholar.org/paper/e3de067afb6033d87e46e530eabf3455c3d58a84

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