Atomic-scale characterization of nitrogen-doped graphite: Effects of dopant nitrogen on the local electronic structure of the surrounding carbon atoms

By T. Kondo, S. Casolo, Tetsuya Suzuki, Taishi Shikano, M. Sakurai, Y. Harada, M. Saito, M. Oshima, M. I. Trioni, G. Tantardini and 1 more. 2012

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We report on the local atomic and electronic structures of a nitrogen-doped graphite surface by scanning tunneling microscopy, scanning tunneling spectroscopy, x-ray photoelectron spectroscopy, and first-principles calculations. The nitrogen-doped graphite was prepared by nitrogen ion bombardment followed by thermal annealing. Two types of nitrogen species were identified at the atomic level: pyridinic-N (N bonded to two C nearest neighbors) and graphitic-N (N bonded to three C nearest neighbors). Distinct electronic states of localized π states were found to appear in the occupied and unoccupied regions near the Fermi level at the carbon atoms around pyridinic-N and graphitic-N species, respectively. The origin of these states is discussed based on experimental results and theoretical simulations.

Subfields: Electrical and Electronic Engineering, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/da0b04ea533a463edd1aa10d90f1c1b35f78e04f