Surface enhanced vibrational spectroscopy

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Single-molecule surface-enhanced Raman spectroscopy. (2012, background): “The SERS effect (17, 18) has a longer and distinguished trajectory that goes back to its controversial origins in the mid-1970s (19–25).”
Quantifying SERS enhancements (2013, background): “By substantially increasing the concentration of analyte, one reaches a regime where SM-SERS events are routinely observed and can be studied (2).”
Resonant plasmonic and vibrational coupling in a tailored nanoantenna for infrared detection. (2008, background): “Until now, no more than 3 orders of magnitude of direct vibration signal enhancement have been achieved in typical SEIRA experiments [5–12] where a metal-particle ensemble is used as substrate.”
Tip-enhanced Raman Spectroscopy - Its status, challenges and future directions (2009, background): “orders of magnitude lower than the IR absorption cross section [ 40 ].”
A review on the fabrication of substrates for surface enhanced Raman spectroscopy and their applications in analytical chemistry. (2011, methodology): “[9] N.P.W. Pieczonka, R.F. Aroca, Chemical Society Reviews 37 (2008) 946.”