Excellent performance of mesoporous Co3O4/MnO2 nanoparticles in heterogeneous activation of peroxymonosulfate for phenol degradation in aqueous solutions

By Hanwen Liang, Hongqi Sun, Archana Patel, Pradeep R. Shukla, Zhonghua Zhu, Shaobin Wang. 2012

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New insights into heterogeneous generation and evolution processes of sulfate radicals for phenol degradation over one-dimensional α-MnO2 nanostructures (2015, background): “As seen, p-benzoquinone and 4hydroxybenzoic acid were the more abundant aromatic intermediates than 1,2-dihydroxybenzene, revealing that hydroxylation took place in the para position predominantly rather than ortho position [14,44].”
Magnetic Fe3O4/carbon sphere/cobalt composites for catalytic oxidation of phenol solutions with sulfate radicals (2014, background): “6 was identified, which indicates the presence of Co3O4 [31].”
Effects of nitrogen-, boron-, and phosphorus-doping or codoping on metal-free graphene catalysis (2015, methodology): “Recently, heterogeneous catalytic oxidation using peroxymonosulfate (PMS, commercially available as Oxone) with cobalt catalysts has been employed for phenol oxidative decomposition [8-10].”