Polybenzimidazole (PBI)/zeolitic imidazolate frameworks (ZIF-8) mixed matrix membranes for pervaporation dehydration of alcohols

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Natural gas purification and olefin/paraffin separation using thermal cross-linkable co-polyimide/ZIF-8 mixed matrix membranes (2013, background): “ZIF-8 (Zn (2methylimidazole)2) is one of the most extensively studied ZIFs [2,28,34–41].”
Pervaporation performance comparison of hybrid membranes filled with two-dimensional ZIF-L nanosheets and zero-dimensional ZIF-8 nanoparticles (2017, background): “Till now, ZIF-8 nanoparticles have been incorporated into polymer matrix (polybenzimidazole (PBI) [37], polyimide [38] and (poly(vinyl alcohol) (PVA) [39,40]) to fabricate hybrid membranes for dehydration of alcohols.”
Enhanced gas separation performance of 6FDA-DAM based mixed matrix membranes by incorporating MOF UiO-66 and its derivatives (2018, background): “Indeed, MOF-containing membranes have been reported to perform better than the current Robeson upper bounds [29] for several gas pairs of great interest: CO2/CH4 (e.g. ZIF-90 with 6FDA-DAM [30], ZIF-8 with PIM-1 [31]), CO2/N2 (e.g. ZIF-7 in Pebax® 1657 [32], ZIF-8 in Pebax® 2533 [33]), and H2/CO2 (e”
Hydrophobic-ZIF-71 filled PEBA mixed matrix membranes for recovery of biobutanol via pervaporation (2013, background): “To date, the studies on MOF-containing MMMs for pervaporation application are still very limited [23,25,26]; especially no studies on biobutanol recovery from real ABE fermentation broth were reported.”