Controlling the Diameter of Polyaniline Nanofibers by Adjusting the Oxidant Redox Potential

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Spectroscopy of thin polyaniline films deposited during chemical oxidation of aniline (2012, background): “…this topic have been reported in liter- ature (Izumi et al., 2005; Konyushenko et al., 2006a; Trchová et al., 2006b; Venancio et al., 2006; Stejskal et al., 2006a, 2008a; Ding et al., 2007; Zhang et al., 2007; Zujovic et al., 2008; Li et al., 2008; Surwade et al., 2009b; Trchová & Stejskal, 2011).”
Polyaniline nanostructures and the role of aniline oligomers in their formation (2010, background): “It has been demonstrated that not only APS, but also cerium(IV) salts [59,336], copper(II) chloride [59], chlorine [47], iodine [337], hydrogen peroxide [52,270,290], iron(III) chloride or sulfate [23,59,44,109,112,158,179,318,326], periodic acid [338], potassium iodate [120], manganese(IV) oxide [2”
Oxidative Polymerization of Aniline: Molecular Synthesis of Polyaniline and the Formation of Supramolecular Structures (2012, background): “The authors of (Ding et al. 2007) revealed interrelation between the value of oxidation potential of oxidizing agents and diameter of one-dimensional PANI particles: lowering the potential leads to decrease in fiber diameter.”
Recent advances in synthesis, physical properties and applications of conducting polymer nanotubes and nanofibers (2011, background): “Up to now, a variety of polyaniline micro/nanostructures such as micro/nanotubes [49,56,57], nanowires/fibers [58–60], hollow microspheres [61,62],”