Mechanisms controlling the durability of thermal barrier coatings

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New material concepts for the next generation of plasma-sprayed thermal barrier coatings (2003, background): “[ 32 ] The oxygen diffusion through YSZ is for the formation of a TGO of minor importance.”
Response of ytterbium disilicate–silicon environmental barrier coatings to thermal cycling in water vapor (2016, methodology): “Raman Spectroscopy, using an inVia microscope (Renishaw, Hoffman Estates, IL, was used to identify the TGO phase [23,24].”
A Fundamental Model of Cyclic Instabilities in Thermal Barrier Systems (2002, positive): “The model embodies an initial geometric imperfection, inspired by the morphology found on actual turbine components (Evans et al., 2001; Gell et al., 1999; Mumm et al., 2001; Spitsberg et al., 2002; Wright and Evans, 1999).”
On a ferroelastic mechanism governing the toughness of metastable tetragonal-prime (t′) yttria-stabilized zirconia (2007, background): “…Mercer et al.1394 delamination caused by strain misfit with the substrate, especially under thermal cycling conditions (Tolpygo & Clarke 1999; Evans et al. 2001; Mumm et al. 2001; Clarke & Levi 2003), (ii) material loss due to erosion and foreign object damage (FOD) (Chen et al. 2003), and…”