Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors

By Carla Marins Goulart, Andressa Esteves-Souza, Carlos Alberto Martínez-Huitle, C. Rodrigues, M. A. Maciel, A. Echevarria. 2013

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Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor (2014, background): “The DGads values listed in Table 4 are around 25 kJ mol , which means that the adsorption of TEE on MS surface belongs to the physisorption and the adsorptive film has an electrostatic character [25,26,32,48–50].”
Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1 M HCl: Experimental and computational study (2015, background): “These organic inhibitors are usually adsorbed on the metal surface via formation of a coordinate covalent bond (chemical adsorption) or the electrostatic interaction between the metal and inhibitor (physical adsorption) [9].”
Enhanced corrosion resistance of mild steel in 1 M HCl solution by trace amount of 2-phenyl-benzothiazole derivatives: Experimental, quantum chemical calculations and molecular dynamics (MD) simulation studies (2017, background): “The observation of depressed capacitive loop in the Nyquist plot of the inhibitors is presumably due to fast absorption of the aforementioned intermediate products [41, 42].”
Experimental and computational investigation on the corrosion inhibition characteristics of mild steel by some novel synthesized imines in hydrochloric acid solutions (2015, background): “This could be explained on the basis of inhibitor adsorption on the metal surface and the adsorption process enhances with increasing inhibitor concentration [45].”