High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites
By C. Wehrenfennig, G. Eperon, M. Johnston, H. Snaith, L. Herz. Advances in Materials, 2013
2,907 citations recorded by the source corpus.
Organolead trihalide perovskites are shown to exhibit the best of both worlds: charge-carrier mobilities around 10 cm2 V−1 s−1 and low bi-molecular charge-recombination constants. The ratio of the two is found to defy the Langevin limit of kinetic charge capture by over four orders of magnitude. This mechanism causes long (micrometer) charge-pair diffusion lengths crucial for flat-heterojunction photovoltaics.
Subfields: Electrical and Electronic Engineering, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/ca7fe051f0e1ffd6df4c8a9a786e094b98a0b7ae
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Citations in the corpus
- Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States (2014, positive): “expected from the Langevin theory [24].”
- Optical transitions in hybrid perovskite solar cells: Ellipsometry, density functional theory, and quantum efficiency analyses for CH3NH3PbI3 (2015, background): “0 m mh = ) [38] and the resulting high mobility (8−38 cm(2)/Vs) [15,22,24,25] in CH3NH3PbI3.”