Catalytic activity of unsupported gold nanoparticles

By Y. Mikami, A. Dhakshinamoorthy, M. Álvaro, H. García. 2013

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This article reviews some of the compelling evidence showing that colloidal gold nanoparticles without any solid support exhibit intrinsic catalytic activity for some of the typical gold-catalyzed reactions including CO oxidation, aerobic oxidation of alcohols and diols, borohydride reductions and carbon–carbon cross coupling reaction among other reactions. A critical view of the state-of-the-art indicating open issues such as the role of the nature and concentration of the ligand and the possibility of preparing colloidal samples with preferential crystallographic planes is provided.

Subfields: Electronic, Optical and Magnetic Materials, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/bf7f720f7978c7a87f23c175bd187ff550d4d7cd

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