Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene

By F. Paulot, J. Crounse, H. Kjaergaard, A. Kürten, Jason M. St. Clair, John H. Seinfeld, Paul O. Wennberg. Science, 2009

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Reactive intermediates revealed in secondary organic aerosol formation from isoprene (2009, methodology): “1C) by OH under low-NOx conditions (3).”
Isoprene Production Via the Mevalonic Acid Pathway in Escherichia coli (Bacteria) (2012, background): “Isoprene reacts with –OH radicals and ozone, and thus, has the potential to play a dominant role on the oxidation capacity of the troposphere [3].”
The Framework for 0-D Atmospheric Modeling (F0AM) v3.1 (2016, neutral): “…(Archibald et al., 2010; Coates and Butler, 2015; Emmerson and Evans, 2009; Knote et al., 2015), evaluation of field observations (Li et al., 2014; Olson et al., 2006; Stone et al., 2011; Wolfe et al., 2014), and analysis of laboratory chamber experiments (Fuchs et al., 2013; Paulot et al., 2009a).”
Anthropogenic and Natural Radiative Forcing (2014, background): “, 2008), although some of those reactions are still poorly understood (Paulot et al., 2009; Peeters et al., 2009; Taraborrelli et al., 2012).”