Phase stability of non-equiatomic CoCrFeMnNi high entropy alloys

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Ni tracer diffusion in CoCrFeNi and CoCrFeMnNi high entropy alloys (2016, background): “Ma and co-workers have argued that solid solutions present in HEA need not be entropy stabilized [4] and ab-initio calculations for CoCrFeMnNi indicate that vibrational, electronic and magnetic entropies are equally important as the configurational one [5].”
Non-equiatomic high entropy alloys: Approach towards rapid alloy screening and property-oriented design (2015, background): “demonstrated the weak dependence of single phase solid solution formability on configurational entropy [22].”
High-entropy alloys: a critical assessment of their founding principles and future prospects (2016, background): “The formation of σ in CrMnFeCoCu, VCrMnCoNi and VMnFeCoNi is also not well predicted by CALPHAD.19,167,213 Indeed, the accurate prediction of intermetallic phases, the formation of which is of great importance to engineering alloys, appears to be problematic for CALPHAD methods in general.”
The fcc solid solution stability in the Co-Cr-Fe-Mn-Ni multi-component system (2017, unknown): “Indeed this method has already been applied to HEA and, although few compositions [11] or only equimolar alloys [12] were studied, the results were promising.”