Metal-organic framework nanosheets: An emerging family of multifunctional 2D materials

By Jingui Duan, Yanshuo Li, Yichang Pan, N. Behera, W. Jin. Coordination chemistry reviews, 2019

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Abstract With infinite assembly and ultrathin nature, metal-organic frameworks nanosheets (MOFNs), as an emerging family of two-dimensional (2D) materials, have attracted extensive interest in fields of material science, chemistry and nanotechnology. Here, we aim to review the recent advances of MOFNs. The assortments of their synthetic methods of top-down, bottom-up and combined strategies are discussed at first, including the comparison of their advantages and limitations. Then, some crucial techniques towards the morphology and microstructure characterization of MOFNs were introduced. We have also discussed the wide ranges of potential applications, especially molecular separation, catalyst, energy conversion, conduction, photofunction, electrochromism and sensing. Finally, the challenges and outlooks for these multi-functional 2D materials were prospected based on current achievements, as well as their unique architectural features.

Subfields: Inorganic Chemistry, Materials Chemistry, Renewable Energy, Sustainability and the Environment

View Paper: https://www.semanticscholar.org/paper/b6117f001763d181e64bf9ecf8e291d81db22bf1