Effect of Structural Parameters on Superconductivity in Fluorine-Free LnFeAsO1-y (Ln = La, Nd)

By Chul-Ho Lee, A. Iyo, H. Eisaki, H. Kitô, M. Fernandez-Diaz, T. Ito, K. Kihou, H. Matsuhata, M. Braden, K. Yamada. 2008

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The crystal structure of LnFeAsO 1- y (Ln = La, Nd) has been studied by the powder neutron diffraction technique. The superconducting phase diagram of NdFeAsO 1- y is established as a function of oxygen content which is determined by Rietveld refinement. The small As–Fe bond length suggests that As and Fe atoms are connected covalently. FeAs 4 -tetrahedrons transform toward a regular shape with increasing oxygen deficiency. Superconducting transition temperatures seem to attain maximum values for regular FeAs 4 -tetrahedrons.

Subfields: Condensed Matter Physics, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/b4d7fd26e68642b0e20dc0cc9706ad4bb6dfa8fa

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In Condensed Matter Physics

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In Electronic, Optical and Magnetic Materials

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