Synthesis of functional polymers with controlled architecture by CRP of monomers in the presence of cross-linkers: From stars to gels

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Nanostructured functional materials prepared by atom transfer radical polymerization (2009, background): “Alternatively, copolymerization of vinyl monomers with a small amount of a divinyl monomer (typically, less than 1 unit per living chain) also yields branched macromolecules and is an attractive synthetic method that eliminates the need to synthesize complex inimer”