Dehydration of cellulose to levoglucosenone using polar aprotic solvents

By Fei Cao, Thomas J. Schwartz, D. McClelland, Siddarth H. Krishna, James A. Dumesic, G. Huber. 2015

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Herein, we report an approach to produce levoglucosenone (LGO) from cellulose in yields up to 51% under mild reaction conditions (170–230 °C; 5–20 mM H2SO4) using polar, aprotic solvents such as tetrahydrofuran (THF). LGO can be used to make a wide variety of chemicals from biomass. The water content and solvent used in the reaction system control the product distribution. LGO is produced from the dehydration of levoglucosan (LGA). LGA is produced from cellulose depolymerization. Increasing the water content leads to the production of 5-hydroxymethyl furfural (HMF), obtaining a maximum HMF yield of 30%.

Subfields: Biomedical Engineering, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/b166a08dfc17aa6f019213f1e05fcf0efc3dd90c