Molecular segregation observed in a concentrated alcohol–water solution

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Interfaces and the driving force of hydrophobic assembly (2005, background): “For example, a few hydrated methane molecules and the alkyl groups of small alcohol molecules mixed with water show insignificant tendencies to cluste”
Fluctuating charge force fields: recent developments and applications from small molecules to macromolecular biological systems (2006, background): “juxtaposition of hydrophilic and hydrophobic moieties leads to anomalous behavior upon mixing of simple alcohols and water; recent experimental [76] and theoretical/simulation [77] studies have directed attention to the solvation structure around the aliphatic and hydroxyl groups of ethanol in order”
Structural analysis of complex materials using the atomic pair distribution function — a practical guide (2003, methodology): “Isotope substitution studies are applied to glasses and liquids (e.g. Petri et al., 2000; Dixit et al., 2002) but are also used to study disordered crystals, e.g. in a study by Louca et al. (1999) on high temperature superconducting cuprates.”