A flexible and self-healing hydrogel electrolyte for smart supercapacitor

By Hui Peng, Yaya Lv, Ganggang Wei, Jiezi Zhou, Xiaojie Gao, K. Sun, Guofu Ma, Z. Lei. Journal of Power Sources, 2019

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Abstract Although the hydrogel electrolytes for flexible energy-storage device have made great progress, it still remains a huge challenge to assemble a smart supercapacitor with high ionic conductivity and excellent self-healing when suffering physical damage. Herein, a novel self-healing hydrogel electrolyte (B-PVA/KCl/GO) is designed and prepared through graphite oxide (GO) doped into a diol-borate ester bonding cross-linked poly(vinyl alcohol) network. It is found that the moderate amount of GO-doped into hydrogel (2.3 wt% GO, 47.5 mS/cm) is obviously improved ionic conductivity compared with bare B-PVA/KCl hydrogel (32.6 mS/cm). Interestingly, the B-PVA/KCl/GO hydrogel electrolyte exhibits excellent self-healing capability that can repair its original configuration with 5 min when it is cut. Moreover, the activated carbon-based supercapacitor with B-PVA/KCl/GO hydrogel electrolyte delivers high specific capacitance of 156 F g−1 at 0.3 A g−1 and can also restore its capacitive performances via 7 times healing cycles without external stimulus. The presented work provides a new strategy to construct a flexible and self-healing hydrogel to apply for wearable electronics, smart apparels or flexible robots.

Subfields: Biomedical Engineering, Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/aecd9dfd3ac0482a88898ed93fb73cd944fe4c18

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