The furan/maleimide Diels–Alder reaction: A versatile click–unclick tool in macromolecular synthesis

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Click hydrogels, microgels and nanogels: emerging platforms for drug delivery and tissue engineering. (2014, background): “The DA click reaction could be reversed at high temperature through the retro-DA reaction, which opens a way to controlled drug release [78].”
Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities (2018, background): “maleimide) to form stable cyclohexene adduct at about 60 ◦C, whereas the retro-DA ncoupling reaction becomes preponderant at a temperature above bout 110 ◦C [46].”