Superconductivity at 38 K in the iron arsenide (Ba1-xKx)Fe2As2.
By M. Rotter, M. Tegel, D. Johrendt. Physical Review Letters, 2008
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The ternary iron arsenide BaFe2As2 becomes superconducting by hole doping, which was achieved by partial substitution of the barium site with potassium. We have discovered bulk superconductivity at T{c}=38 K in (Ba1-xKx)Fe2As2 with x approximately 0.4. The parent compound BaFe2As2 crystallizes in the tetragonal ThCr2Si2-type structure, which consists of (FeAs);{delta-} iron arsenide layers separated by Ba2+ ions. BaFe2As2 is a poor metal and exhibits a spin density wave anomaly at 140 K. By substituting Ba2+ for K+ ions we have introduced holes in the (FeAs);{-} layers, which suppress the anomaly and induce superconductivity. The T{c} of 38 K in (Ba0.6K0.4)Fe2As2 is the highest in hole doped iron arsenide superconductors so far. Therefore, we were able to expand this class of superconductors by oxygen-free compounds with the ThCr2Si2-type structure.
Subfields: Condensed Matter Physics, Electronic, Optical and Magnetic Materials
View Paper: https://www.semanticscholar.org/paper/aa5a467f0cc8ea59dfa998ee6902867e143ff911
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Citations in the corpus
- Superconductivity in iron compounds (2011, background): “In addition to doping-induced superconductivity, three Fe-containing 122 compounds superconduct without doping, KFe2As2 (Tc 3:8 K, Rotter et al., 2008a), RbFe2As2 (Tc 2:6 K, Bukowski et al., 2010), and CsFe2As2 (Tc ¼ 2:6 K, Sasmal et al. (2008).”