Coupling between electronic and structural degrees of freedom in the triangular lattice conductor NaxCoO2

By Q. Huang, M. Foo, R. Pascal, J. Lynn, B. Toby, T. He, H. Zandbergen, R. Cava. 2004

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The ambient temperature crystal structures of compounds in the NaxCoO2 family, for 0.34 , x 1.0, determined by powder neutron diffraction, are reported. The structures consist of triangular CoO 2 layers with Na ions distributed in intervening charge reservoir layers. The shapes of the CoO 6 octahedra that make up the CoO2 layers are found to be critically dependent on the electron count and on the distribution of the Na ions in the intervening layers, where two types of Na sites are available. Correlation of the shapes of cobalt-oxygen octahedra, the Na ion positions, and the electronic phase diagram in NaxCoO2 is made, providing an example of how structural and electronic degrees of freedom can be coupled in electrically conducting triangular lattice systems.

Subfields: Condensed Matter Physics, Materials Chemistry, Polymers and Plastics

View Paper: https://www.semanticscholar.org/paper/a5d38a250fbc65f64354dd0ecdf719430862b1b7

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