Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations.

By Yizhou Zhu, Xingfeng He, Yifei Mo. ACS Applied Materials and Interfaces, 2015

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A review of the degradation mechanisms of NCM cathodes and corresponding mitigation strategies (2023, background): “Firstly, CEI, artificial (as in the case of coatings) or “natural” (formed during the operation, as in the case of CEI growth in the cell during cycling), can mitigate the Li chemical potential discrepancy between the electrolyte and electrode at the interfaces[192].”
The Thermal Stability of Lithium Solid Electrolytes with Metallic Lithium (2020, neutral): “Among these SEs, LATP and LAGP are highly reactive with Li metal, with decomposition energies of over 60 kJ/mol of SEs and Li, while LLZO is almost thermodynamically stable with Li metal within typical DFT errors.(28) Although the interfacial reaction is thermodynamically favorable, we expect it is ”