High-Figure-of-Merit Thermoelectric La-Doped A-Site-Deficient SrTiO3 Ceramics

By Zhilun Lu, Huairuo Zhang, W. Lei, Derek C. Sinclair, I. Reaney. 2016

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The structure and thermoelectric (TE) properties of La-doped, A-site-deficient SrTiO3 (Sr1–3x/2LaxTiO3) ceramics sintered in air and N2/5% H2 have been investigated. Air-sintered ceramics with 0.10 ≤ x 0.50 are orthorhombic with an a–a–c+ tilt system and long-range VA ordering. x = 0.15 sintered in N2/5% H2 shows the largest dimensionless TE figure-of-merit ZT = 0.41 at 973 K reported for n-type SrTiO3-based ceramics, suggesting that the accommodation of La throu...

Subfields: Electronic, Optical and Magnetic Materials, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/a4ae6f8c5593ed97ce3175051893ec6079a5cd23

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