Strong Correlations from Hund’s Coupling

By A. Georges, L. Medici, J. Mravlje. 2012

730 citations recorded by the source corpus.

Strong electronic correlations are often associated with the proximity of a Mott-insulating state. In recent years however, it has become increasingly clear that the Hund’s rule coupling (intra-atomic exchange) is responsible for strong correlations in multiorbital metallic materials that are not close to a Mott insulator. Hund’s coupling has two effects: It influences the energetics of the Mott gap and strongly suppresses the coherence scale for the formation of a Fermi liquid. A global picture has emerged recently, which emphasizes the importance of the average occupancy of the shell as a control parameter. The most dramatic effects occur away from half-filling or single occupancy. We review the theoretical understanding and physical properties of these Hund’s metals, together with the relevance of this concept to transition-metal oxides (TMOs) of the 3d, and especially 4d, series (such as ruthenates), as well as to the iron-based superconductors (iron pnictides and chalcogenides).

Subfields: Condensed Matter Physics, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/a3c37fbf39c9ac17ef9227fc3cdc34cdb78add0b

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In Condensed Matter Physics

  1. A. D. L. Torre
  2. A. Georges
  3. S. Sachdev

In Electronic, Optical and Magnetic Materials

  1. A. D. L. Torre
  2. A. Georges

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