Epitaxial growth of two-dimensional stanene.
By F. Zhu, Weijiong Chen, Yong Xu, C. Gao, D. Guan, Canhua Liu, D. Qian, Shoucheng Zhang, J. Jia. Nature Materials, 2015
1,567 citations recorded by the source corpus.
Following the first experimental realization of graphene, other ultrathin materials with unprecedented electronic properties have been explored, with particular attention given to the heavy group-IV elements Si, Ge and Sn. Two-dimensional buckled Si-based silicene has been recently realized by molecular beam epitaxy growth, whereas Ge-based germanene was obtained by molecular beam epitaxy and mechanical exfoliation. However, the synthesis of Sn-based stanene has proved challenging so far. Here, we report the successful fabrication of 2D stanene by molecular beam epitaxy, confirmed by atomic and electronic characterization using scanning tunnelling microscopy and angle-resolved photoemission spectroscopy, in combination with first-principles calculations. The synthesis of stanene and its derivatives will stimulate further experimental investigation of their theoretically predicted properties, such as a 2D topological insulating behaviour with a very large bandgap, and the capability to support enhanced thermoelectric performance, topological superconductivity and the near-room-temperature quantum anomalous Hall effect.
Subfields: Atomic and Molecular Physics, and Optics, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/a1a5e34ccd4c18532027863027bbb8b98c27c06f
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In Materials Chemistry
Citations in the corpus
- Angle-resolved photoemission studies of quantum materials (2020, neutral): “Photoemission studies in these systems have mostly focused on eV-scale band structure identi- 44 fication (Feng et al., 2017, 2016; Mo, 2017; Vogt et al., 2012; Zhu et al., 2015a), with the major limiting factor being sample stability and availability especially towards the less metallic side.”
- First-principles investigation of mechanical properties of silicene, germanene and stanene (2017, background): “of other two-dimensional (2D) compounds including hexagonal boron-nitride [6,7], graphitic carbon nitride [8,9] silicene [10,11], germanene [12], stanene [13], transition metal dichalcogenides such as MoS2 and WS2 [14–16] and phosphorene [17,18].”