Self-Discharge in Electrochemical Capacitors: A Perspective Article

By H. Andreas. 2015

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This perspective article outlines some of the key considerations and literature that have been published on self-discharge in electrochemical capacitors. While for some consumer applications self-discharge is not considered to be a significant issue (e.g. energy storage from regenerative breaking) in applications where the electrochemical capacitor is stored in the charged state for significant times (e.g. coupled with a battery in a cell phone), the impact on energy, power and recharging frequency of both the capacitor and battery can be significant. A description is provided here of the common methods of self-discharge study: half cell vs. full cell measurements and open-circuit potential decay versus float currents. A description of some of the models used to evaluate faradaic self-discharge is presented, with a synopsis of the important aspects of the many available charge redistribution models. An overview of the current self-discharge mechanisms for various ECs is provided, highlighting that for many systems there are significant factors of the self-discharge process which remain unknown. Finally, some future directions are anticipated for the field of self-discharge in electrochemical capacitors. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial No Derivatives 4.0 License (CC BY-NC-ND, http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial reuse, distribution, and reproduction in any medium, provided the original work is not changed in any way and is properly cited. For permission for commercial reuse, please email: oa@electrochem.org. [DOI: 10.1149/2.0081505jes] All rights reserved.

Subfields: Automotive Engineering, Electronic, Optical and Magnetic Materials, Polymers and Plastics

View Paper: https://www.semanticscholar.org/paper/9f986ee61f08f485f90cf539965ad4950c22defc

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In Automotive Engineering

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