Structural distortion and magnetism of BiFeO3 epitaxial thin films: A Raman spectroscopy and neutron diffraction study
By H. Béa, Manuel Bibes, S. Petit, Jens Kreisel, A. Barthélémy. 2007
199 citations recorded by the source corpus.
A previous study of the growth conditions has shown that single-phase BiFeO3 thin films can only be obtained in a narrow pressure–temperature window and that these films display a weak magnetic moment. Here, we study in more detail the structure and the magnetism of single-phase BiFeO3 films by means of reciprocal space mapping, Raman spectroscopy and neutron diffraction. X-ray and Raman data suggest that the BiFeO3 structure is tetragonal for 70 nm thick films and changes to monoclinic for 240 nm thick films, thus remaining different from that of the bulk (rhombohedral) structure. In the 240 nm monoclinically distorted film, neutron diffraction experiments allow the observation of a G-type antiferromagnetic order as in bulk single crystals. However, the satellite peaks associated with the long-wavelength cycloid present in bulk BiFeO3 are not observed. The relevance of these findings for the exploitation of the magnetoelectric properties of BiFeO3 is discussed.
Subfields: Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/9c3f8b6684fd807ef498576feb99b2b1bac7731e
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In Electrical and Electronic Engineering
In Electronic, Optical and Magnetic Materials
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Citations in the corpus
- Oxide Spintronics (2007, background): “Its antiferromagnetic [283]–[285], [300] character has been used to induce an exchange bias on a soft ferromag-”