High Electrical Conductivity in a 2D MOF with Intrinsic Superprotonic Conduction and Interfacial Pseudo-capacitance

By Jian Su, Wen He, Xiaomin Li, Lei Sun, Hai‐Ying Wang, Y. Lan, Mengning Ding, J. Zuo. 2020

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Summary Two-dimensional (2D) conductive metal-organic frameworks (MOFs), whose advanced electrical properties accompany their intrinsic structural characteristics, represent an exciting new class of 2D atomic crystals for the van der Waals integration of novel heterostructures and the development of novel nano/quantum devices. Guided by topology, we report two 2D MOFs (1 and 2) constructed via combination of [In(COO)4]− metal nodes and tetratopic tetrathiafulvalene (TTF)-based linkers, with ultrahigh proton conductivity (6.66 × 10−4 and 1.30 × 10−2 S cm−1 for 1 and 2, respectively). Additionally, high electrical conductivity was simultaneously achieved with the pure protonic nature of the 2D MOF 2. The electrical conduction at the MOF-metal interface is enabled by the redox-switchable behavior of the TTF-based ligands. This unique charge-transport mechanism, protonic/pseudo-capacitance coupling, offers a new strategy for utilizing the ionic conductivity from MOFs to construct functional electronic devices.

Subfields: Electronic, Optical and Magnetic Materials, Inorganic Chemistry, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/98e5b20fe1c899f79748b0acb33552389fe004f4