Covalent organic frameworks.
By K. Tan, Samrat Ghosh, Zhiyong U Wang, Fuxiang Wen, D. Rodríguez‐San‐Miguel, Jie Feng, Ning Huang, Wen Wang, F. Zamora, Xinliang Feng and 2 more. Chemical Society Reviews, 2012
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Covalent organic frameworks (COFs) are a class of crystalline porous polymers that allow the atomically precise integration of organic units to create predesigned skeletons and nanopores. They have recently emerged as a new molecular platform for designing promising organic materials for gas storage, catalysis, and optoelectronic applications. The reversibility of dynamic covalent reactions, diversity of building blocks, and geometry retention are three key factors involved in the reticular design and synthesis of COFs. This tutorial review describes the basic design concepts, the recent synthetic advancements and structural studies, and the frontiers of functional exploration.
Subfields: Inorganic Chemistry, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/956cf2b6a5088eec6f8cf24a9fad981d63c3eb7c
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