Review—Solid Electrolytes in Rechargeable Electrochemical Cells
By John B. Goodenough, Preetam Singh. 2015
214 citations recorded by the source corpus.
Solid electrolytes may be used where the electrode reactants are gaseous as in a rechargeable oxide fuel cell or are liquids as in a cell of a rechargeable Na-S battery; porous polymer/oxide composites may be used as a separator where one electrode is a flow-through liquid containing a soluble redox molecule. Where two solid electrodes interact reversibly across an electrolyte, a solid-electrolyte may be used (i) as a separator in a dual liquid-electrolyte cell, (ii) in an all-solid-state battery, or (iii) in contact with an alkali-metal anode on one side and a liquid electrolyte on the other side. A solid-electrolyte interface with the anode would also block from reaching the anode soluble intermediate species of a solid-sulfur cathode reaction in a liquid catholyte. We discuss strategies for realizing the different strategies and introduce the concept of water-solvated glass/amorphous solid cation electrolytes/dielectrics. © The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. [DOI: 10.1149/2.0021514jes] All rights reserved.
Subfields: Electrical and Electronic Engineering, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/930164d4d4aaace575ffe70cf897aa5e1cf9e4d8
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Citations in the corpus
- Structural Design of Lithium–Sulfur Batteries: From Fundamental Research to Practical Application (2018, background): “Thirdly, the sulfide-based electrolytes are chemically and electrochemical unstable, which until now has been difficult to address for mass production [361, 365, 366].”