Atomic-size effect and solid solubility of multicomponent alloys

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High-entropy alloys: a critical assessment of their founding principles and future prospects (2016, methodology): “Others have used alternative means of comparison – for instance, Singh et al.173 have suggested the use the parameter L = DSmix/d2, while Wang et al.266,271 replaced δ with a new parameter for the measure of atomic size mismatch, arguing that δ does not distinguish effectively enough between systems”
An assessment on the future development of high-entropy alloys: Summary from a recent workshop (2015, neutral): “It was argued that the atoms with the maximum and minimum sizes play a decisive role in determining the packing stability in HEAs [19].”
Laves-phase formation criterion for high-entropy alloys (2017, background): “175.(21) (iii) VEC and electronegativity parameters, broadly speaking, take into account similarity of the electronic structures of atoms of constitutive elements.”
Predicting the formation and stability of single phase high-entropy alloys (2016, background): “There are some associated errors with this model [29] but more concerning is that it only represents an ideal solution and assumes a 50/50 mixture will yield the largest magnitude in the enthalpy of mixing [30].”