Improving the mechanical properties of graphene oxide based materials by covalent attachment of polymer chains
By Manuela Cano, U. Khan, T. Sainsbury, A. O’Neill, Zhiming Wang, I. Mcgovern, W. Maser, Ana M. Benito, Jonathan N. Coleman. Carbon, 2013
272 citations recorded by the source corpus.
Abstract We report on the modification of graphene oxide (GO) with poly(vinyl alcohol) (PVA) leading to the mechanical improvement of GO based materials. First, GO was covalently functionalised with PVA by esterification of carboxylic groups on GO with hydroxyl groups of PVA resulting in functionalised f-(PVA)GO. This was carried out for PVA of six different molecular weights. This functionalised graphene oxide could be formed into a paper-like material by vacuum filtration. Papers prepared from f-(PVA)GO showed significant increases in mechanical properties compared to those prepared with GO or with simple mixtures of GO and PVA. The best performance was achieved for PVA functional groups with molecular weights between 50 and 150 kg/mol. Improvements in Young’s moduli of 60% and tensile strength of 400% were observed relative to GO-only paper. The improved mechanical properties are attributed to enhanced inter-flake stress transfer due to the covalently bonded PVA. Second, functionalised f-(PVA)GO was used as filler in PVA-based composites. The application of a pre-selection method allowed the use of only the largest functionalised f-(PVA)GO flakes. This resulted in substantially reinforced PVA–f-(PVA)GO composites. Both modulus and strength increased by 40% relative to the pure polymer for f-(PVA)GO loadings below 0.3 vol.%.
Subfields: Biomedical Engineering, Materials Chemistry, Polymers and Plastics
View Paper: https://www.semanticscholar.org/paper/90278e812f30474206db0a6d4dc86f4b5ababfc9
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Citations in the corpus
- Tuning the absorption of ultraviolet spectra and optical parameters of aluminum doped PVA based solid polymer composites (2015, background): “The existence of strong intermolecular and intramolecular hydrogen bonding in PVA was confirmed from the FTIR analysis, due to the presence of OH groups [6].”
- Gas Barrier Performance of Graphene/Polymer Nanocomposites (2015, background): “(25) is derived assuming that graphene layers in adjacent layers do not influence each other.”