Physical characterization of the charging process of a Li-ion battery and prediction of Li plating by electrochemical modelling

By Nathalie Legrand, B. Knosp, P. Desprez, F. Lapicque, Stéphane Raël. 2014

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Modeling and simulation of inhomogeneities in a 18650 nickel-rich, silicon-graphite lithium-ion cell during fast charging (2018, methodology): “Using the single p2D model [67, 68, 69], lithium plating can be indicated when the potential drop (Φs − Φl) at the particle surface and the anodeseparator interface (x = Lneg) falls below 0 V without implementing actual plating kinetics.”
Interplay of Lithium Intercalation and Plating on a Single Graphite Particle (2021, background): “Solid diffusion limitation Li concentration in graphite (c) c = 1 at graphite surface Legrand et al.(20) ll”
A new on-line method for lithium plating detection in lithium-ion batteries (2020, background): “The limiting factor is reported to be the deposition of metallic lithium on the NE surface that occurs when the NE potential (NEP) reduces below the lithium reference potential because of the reduced kinetics (such as a reduced intercalation and increased interfacial potential drops [4, 11]).”