Materials designing of metal borohydrides: Viewpoints from thermodynamical stabilities

By Haiwen Li, S. Orimo, Y. Nakamori, K. Miwa, Nobuko Ohba, S. Towata, A. Züttel. 2007

162 citations recorded by the source corpus.

Subfields: Biomaterials, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/85c0abba01290aa048f136f04defdc5558dc197c

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In Materials Chemistry

1. Haiwen Li
2. S. Orimo
3. U. Demirci
4. Yigang Yan
5. C. Jensen
6. A. Züttel
7. T. Jensen
8. P. Miele

Citations in the corpus

• Complex metal hydrides for hydrogen, thermal and electrochemical energy storage (2017, background): “Additionally, a relationship between the Pauling electronegativity of the metal cation and the thermal stability of the metal borohydride has been established as higher electronegativity results in lower decomposition temperature, see Figure 2 [2,110,111].”
• Recent Progress in Metal Borohydrides for Hydrogen Storage (2011, methodology): “Inspired by this finding, an approach of producing multi cation borohydrides MM’(BH4)n, in which M and M’ have different electronegativities has been proposed to precisely tailor the thermodynamic stability [107].”
• Boron‐based hydrides for chemical hydrogen storage (2013, background): “The attractive feature is thatM andM’ have different electronegativities, and this may permit to tailor the thermodynamic stability of the resulting borohydrides [113].”